SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name:

Zeolitni težki kompound / Zeolite heavy compound / Zeolith Heavy Compound HC8

Creation date: 31.3.2008 · Revision: 26.6.2020 · Version: 5.0

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/joW77

1.1. Product identifier

Product name

Zeolitni težki kompound / Zeolite heavy compound / Zeolith Heavy Compound HC8

Synonyms

HC8

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Industrial use.

Uses advised against

not known.

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Phone: +386 2 7991 200
Fax: +386 2 7991 230
E-mail: info@silkem.si

1.4. Emergency telephone number

112

+386 2 7991 208 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the product is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Pictograms not applicable according to Regulation 1272/2008.

2.2.2. Contains:

-

2.2.3. Special provisions

The product is not classified as dangerous according to regulations.

2.3. Other hazards

The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

3. Composition/information on ingredients

Product description

EINECS: 215-283-8 and CAS: 1318-02-1 are merely used for information as related numbers and as a pre-registration identifier. EINECS numbers mentionned here have been designated by ECHA after registration.

3.1. Substances

For mixtures see 3.2.

3.2. Mixtures

Name CAS
EC
Index
% Classification according to Regulation (EC)
No 1272/2008 (CLP)
Specific Conc. Limits Classification according to directive 67/548/EEC or 99/45/EC REACH Registration No.
Zeolite, cuboidal, crystalline, synthetic, non-fibrous 1318-02-1
930-915-9
-
87-91 not classified not classified 01-2119429034-49-0017
2-propenoic acid, polymer with 2,5-furandione, sodium salt 52255-49-9
610-814-3
-
8-10 not classified not classified -

4. First aid measures

4.1. Description of first aid measures

General notes

When in doubt or if feeling unwell seek medical assistance.

Following inhalation

Remove patient to fresh air - move out of dangerous area. Ventilate the premises. Inhale fresh air. If symptoms develop and persist, seek medical attention.

Following skin contact

Product is not irritating to the skin. Areas of the body that have come into contact with the product must be rinsed with water.

Following eye contact

If substance has got into eyes, immediately wash out with plenty of water. If irritation persists, seek professional medical attention.

Following ingestion

In case of doubt or if feeling unwell seek medical help.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Coughing, sneezing, nasal discharge, labored breathing.
Symptoms include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness.

Skin contact

On contact with skin causes irritation and redness.

Eye contact

Redness, tearing, pain.
Symptoms may include: rubescence, edema, pain and lachrymation.

Ingestion

Irritates digestive organs - mouth, gullet, digestive tract.

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

-

5.3. Advice for firefighters

Protective actions

In case of fire or heating do not breathe fumes/vapours.

Special protective equipment for firefighters

In case of fire: Wear suitable respiratory equipment - self-contained breathing apparatus and full protective equipment.

Additional information

Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8). Thoroughly clean hands after use or contact.

Emergency procedures

Avoid dust generation.

6.1.2. For emergency responders

Wear appropriate personal protective equipment!

6.2. Environmental precautions

If accidental large entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Pick up mechanically and remove it in accordance with regulation.

6.3.3. Other information

-

6.4. Reference to other sections

See also Sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Take precautionary measures against static discharges.

Measures to prevent aerosol and dust generation

Prevent dusting. Ensure good ventilation and extraction.

Measures to protect the environment

Avoid release to the environment.

7.1.2. Advice on general occupational hygiene

Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place. Keep away from food, drink and animal feeding stuffs. This product is hygroscopic.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

13

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational exposure limit values

Name (CAS) Limit values Short-term exposure limit Remarks Biological Tolerance Values
ml/m3
(ppm)
mg/m3
ml/m3
(ppm)
mg/m3
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) 10 WEL long-term, inhalable
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) 4 WEL long-term, respirable

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

8.1.3. DNEL/DMEL values

For components

Name Type Exposure route Exposure frequency Value Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) Worker inhalation long term () 3 mg/m³
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) Worker dermal long term () 2,5 mg/kg bw/day

8.1.4. PNEC values

For components

Name Exposure route Value Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) fresh water 3,2 mg/L
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) marine water 0,32 mg/L
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) soil 600 mg/kg dw

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice.

Organisational measures to prevent exposure

Keep eyewash bottles or personal eyewash units available.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in areas with increased concentration.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN 166).

Hand protection

Protective gloves (EN 374).

Skin protection

Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345:2011).

Respiratory protection

Not needed under normal use and adequate ventilation. Mask with dust filter (P2) or FFP2 (EN 149).

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: white
- Odour: odourless

Important health, safety and environmental information

- pH 10 – 11
- Melting point/freezing point No information.
- Initial boiling point/boiling range No information.
- Flash point No information.
- Evaporation rate No information.
- Flammability (solid, gas) No information.
- Explosion limits (vol%) No information.
- Vapour pressure No information.
- Vapour density No information.
- Density Bulk density:
700 – 800 kg/m3
- Solubility Water:
insoluble
- Partition coefficient No information.
- Auto-ignition temperature No information.
- Decomposition temperature No information.
- Viscosity No information.
- Explosive properties No information.
- Oxidising properties No information.
- Particle characteristics No information.

9.2. Other information

- Remarks: Hygroscopic.

10. STABILITY AND REACTIVITY

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Product is stable under normal conditions.

10.3. Possibility of hazardous reactions

The product is stable under recommended storage and handling conditions.

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage. Protect from moisture and water - keep in dry place.

10.5. Incompatible materials

Not known.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected.

11. Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

(a) Acute toxicity

NameExposure routeTypeSpeciesTimeValueMethodRemark
For productinhalationLC50rat4 h 18,3 mg/ldust/aerosol
For productdermalLD50rabbit 2000 mg/kg
For productoralLD50rat 10000 mg/kg
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)oralLD50Dog1000 – 31600 mg/kg
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)oralLD50rat5000 – 31600 mg/kg

(b) Skin corrosion/irritation

NameSpeciesTimeResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)Non-irritant.

(c) Serious eye damage/irritation

NameSpeciesTimeResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)It may cause a slight and transient irritation to the eyes.Apart from mild congestion after 2 hours after application of the preparation, which has disappeard within 24 hours, no inflammation changes of conjunctiva mucosa have been observed there.

(d) Respiratory or skin sensitisation

NameExposure routeSpeciesTimeResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)-Non sensitising.

(e) (Germ cell) mutagenicity

NameTypeSpeciesTimeResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)Negative.

(f) Carcinogenicity

NameExposure routeTypeSpeciesTimeValueResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)negative

(g) Reproductive toxicity

NameReproductive toxicity typeTypeSpeciesTimeValueResultMethodRemark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1)--Negative.

Summary of evaluation of the CMR properties

No information.

(h) STOT-single exposure

No information.

(i) STOT-repeated exposure

No information.

(j) Aspiration hazard

No information.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information.

11.2.2. Other information

No information.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For product
Type Value Exposure time Species Organism Method Remark
EC50 560 – 1000 mg/L 72 h algae
LC50 1800 – 3200 mg/L 96 h fish
For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) EC50 > 100 mg/L 48 h daphnia
LC50 > 680 mg/L 96 h fish
EC50 > 300 mg/L 96 h algae

12.1.2. Chronic (long-term) toxicity

For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) NOEC > 86,7 mg/l fish
NOEC 32 mg/l aquatic invertebrate
NOEC > 200 mg/l sediment organisms
LC50 9000 mg/kg soil dw 23 days Terrestrial plants OECD 208 seedling emergence
EC50 9000 mg/kg soil dw days Terrestrial plants OECD 208 seedling growth
NOEC 5000 mg/kg soil dw Terrestrial plants OECD 208

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

For components
Substance (CAS Nr.) Environment Type / Method Half Time Evaluation Method Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) water hydrolysis The hydrolysis rate is accelerated at high and low pH and is retarded by high concentrations of hydrolysis products
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) water hydrolysis The hydrolytic reaction results in the formation of natural aluminosilicates such that natural constituents of soil, sediment and water are formed

12.2.2. Biodegradation

No information.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

For components
Substance (CAS Nr.) species Organism Value Duration Evaluation Method Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) - Does not bioaccumulate.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

For components
Substance (CAS Nr.) Type Criterion Value Evaluation Method Remark
Zeolite, cuboidal, crystalline, synthetic, non-fibrous (1318-02-1) Soil Not amenable to biodegradation. In practice zeolite improve nutrient balance in soil.

12.5. Results of PBT and vPvB assessment

No evaluation.

12.6. Endocrine disrupting properties

No information.

12.7. Additional information

For product

Avoid release to the environment.

For components

Substance: Zeolite, cuboidal, crystalline, synthetic, non-fibrous

WGK: 0

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Waste should be handled in accordance with local or national regulations

Waste codes / waste designations according to LoW

06 02 99 - wastes not otherwise specified

Packaging

Deliver completely emptied containers to approved waste disposal authorities.

Waste codes / waste designations according to LoW

15 01 02 - plastic packaging

13.1.2. Waste treatment-relevant information

Disposal in accordance with the Rules on the management of waste.

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number or ID number

Not applicable.

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

NO.

14.6. Special precautions for user

Not applicable.

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

-

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

-

List of relevant H phrases

-

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under Section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.