SAFETY DATA SHEET according to Regulation 1907/2006
Creation date: 27.1.2012
The product names refer to additional codes representing different material grades: SPINEL SP67, SPINEL SP78, SPINEL SP90
SPINEL (CAS: 1302-67-6, EC: 215-105-9)
Raw material in the refractories, ceramics, glass and chemical industries, abrasives, polishing aids; use as an additive, filler, pigment
SILKEM, d. o. o.
+386 2 7991 208 (7h - 15h)
According to the regulation, the product is not classified as hazardous.
Pictograms not applicable according to Regulation 1272/2008.
The product is not classified as dangerous according to regulations.
The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).
|%||Classification according to Regulation (EC)
No 1272/2008 (CLP)
|Specific Conc. Limits||Classification according to directive 67/548/EEC or 99/45/EC||REACH Registration No.|
|>99||not classified||not classified||01-2119457267-32-0008|
For substances see 3.1.
Person giving first aid should properly protect himself.
Remove patient to fresh air - move out of dangerous area. If symptoms develop and persist, seek medical attention.
Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.
Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.
Rinse mouth thoroughly with water. In case of doubt or if feeling unwell seek medical help. Show the physician the safety data sheet or label.
No symptoms are expected.
No irritant effects.
No symptoms are expected.
No symptoms are expected.
The product is not combustible. Use the usual extinguishing measures (carbon dioxide (CO2), dry chemical, foam; water spray) Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Full water jet.
Select according to conditions and other factors.
Use personal protective equipment (Section 8).
Ensure adequate ventilation.
Prevent contamination of soil and ground water.
Collect the product and recycle it for reuse. Take up mechanically and collect in suitable container and dispose according to current regulations.
See also Sections 8 and 13.
Ensure adequate ventilation.
Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe dust.
Keep in a cool, dry and well ventilated place.
|Name (CAS)||Limit values||Short-term exposure limit||Remarks||Biological Tolerance Values|
|SPINEL (1302-67-6)||5||OSHA/TWA, respiratoric dust|
|SPINEL (1302-67-6)||15||OSHA/TWA, total dust|
|SPINEL (1302-67-6)||4||WEL long-term, respirable|
|SPINEL (1302-67-6)||10||WEL long-term, inhalable|
BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2012+A1:2015 Workplace exposure. General requirements for the performance of procedures for the measurement of chemical agents. BS EN 689:2018 Workplace exposure. Measurement of exposure by inhalation to chemical agents. Strategy for testing compliance with occupational exposure limit values.
Use good personal hygiene practices – wash hands at breaks and when done working with material.
Provide good ventilation and local exhaust in areas with increased concentration.
Safety glasses with side protection (EN 166).
Protective gloves (EN 374).
Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345).
Not needed under normal use and adequate ventilation. In case of insufficient ventilation wear suitable respiratory protection. Mask with dust filter (P2) or FFP2 (EN 149). Wear a mask with a filter for dust/aerosols - FFP3 (EN 149). 'High/elevated concentrations' means that the occupational exposure limit values have been exceeded.
|-||pH||6 – 9,5|
|-||Melting point/freezing point||< 2135 °C|
|-||Initial boiling point/boiling range||No information.|
|-||Flash point||No information.|
|-||Evaporation rate||No information.|
|-||Flammability (solid, gas)||No information.|
|-||Explosion limits (vol%)||No information.|
|-||Vapour pressure||No information.|
|-||Vapour density||No information.|
3 – 3,4
|-||Partition coefficient||No information.|
|-||Auto-ignition temperature||No information.|
|-||Decomposition temperature||No information.|
|-||Explosive properties||No information.|
|-||Oxidising properties||No information.|
|-||Solid contents||900 – 1500 g/l|
Stable under normal conditions.
Product is stable under normal conditions of use, recommended handling and storage conditions.
There are no known hazardous reactions.
No special precautions required. Consider the directions for use and storage.
Under normal use conditions no hazardous decomposition products are expected.
|SPINEL (1302-67-6)||dermal||LD50||rat||1000 – 3400 mg/kg|
|SPINEL (1302-67-6)||inhalation||LC50||rat||4 h||5,1 – 4000 mg/l|
|Substance (CAS Nr.)||Type||Value||Exposure time||Species||Organism||Method||Remark|
|SPINEL (1302-67-6)||LC50||35 – 54 mg/L||96 h||fish|
|EC50||3,6 – 299 mg/L||2 min||daphnia|
|LC50||0,352 – 10 mg/L||14 days||algae|
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
Product is not classified as dangerous for environment.
Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste.
Deliver completely emptied containers to approved waste disposal authorities.
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative