SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU

Product name:

SPINEL

Creation date: 27.1.2012 · Revision: 30.4.2020 · Version: 2.0

1. Identification of the substance/mixture and of the company/undertaking

chemius.net/vKJ44

1.1. Product identifier

Product name

SPINEL

Synonyms

The product names refer to additional codes representing different material grades: SPINEL SP67, SPINEL SP78, SPINEL SP90 (all sizes)

Name

SPINEL (CAS: 1302-67-6, EC: 215-105-9)

REACH Registration number

01-2119457267-32-0008

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Raw material in the refractories, ceramics, glass and chemical industries, abrasives, polishing aids; use as an additive, filler, pigment

Uses advised against

not known.

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Phone: +386 2 7991 200
Fax: +386 2 7991 230
E-mail: info@silkem.si

1.4. Emergency telephone number

112

+386 2 7991 208 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the product is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Pictograms not applicable according to Regulation 1272/2008.

2.2.2. Contains:

2.2.3. Special provisions

The product is not classified as dangerous according to regulations.

2.3. Other hazards

The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

3. Composition/information on ingredients

3.1. Substances

Name	CAS EC Index	%	Classification according to Regulation (EC) No 1272/2008 (CLP)	Specific Conc. Limits	Classification according to directive 67/548/EEC or 99/45/EC	REACH Registration No.
SPINEL	1302-67-6 215-105-9 -	>99	not classified		not classified	01-2119457267-32-0008

3.2. Mixtures

For substances see 3.1.

4. First aid measures

4.1. Description of first aid measures

General notes

Person giving first aid should properly protect himself.

Following inhalation

Remove patient to fresh air - move out of dangerous area. If symptoms develop and persist, seek medical attention.

Following skin contact

Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.

Following eye contact

Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.

Following ingestion

Rinse mouth thoroughly with water. In case of doubt or if feeling unwell seek medical help. Show the physician the safety data sheet or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

No symptoms are expected.

Skin contact

No irritant effects.

Eye contact

No symptoms are expected.

Ingestion

No symptoms are expected.

4.3. Indication of any immediate medical attention and special treatment needed

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

The product is not combustible. Use the usual extinguishing measures (carbon dioxide (CO₂), dry chemical, foam; water spray) Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

5.3. Advice for firefighters

Protective actions

Special protective equipment for firefighters

Select according to conditions and other factors.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8).

Emergency procedures

Ensure adequate ventilation.

6.1.2. For emergency responders

6.2. Environmental precautions

Prevent contamination of soil and ground water.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

6.3.2. For cleaning up

Collect the product and recycle it for reuse. Take up mechanically and collect in suitable container and dispose according to current regulations.

6.3.3. Other information

6.4. Reference to other sections

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Ensure adequate ventilation.

Measures to prevent aerosol and dust generation

Prevent dusting.

Measures to protect the environment

7.1.2. Advice on general occupational hygiene

Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe dust.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in a cool, dry and well ventilated place.

7.2.2. Packaging materials

7.2.3. Requirements for storage rooms and vessels

7.2.4. Storage class

7.2.5. Further information on storage conditions

7.3. Specific end use(s)

Recommendations

Industrial sector specific solutions

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational exposure limit values

Name (CAS)	Limit values		Short-term exposure limit		Remarks	Biological Tolerance Values
Name (CAS)	ml/m³ (ppm)	mg/m³	ml/m³ (ppm)	mg/m³	Remarks	Biological Tolerance Values
SPINEL (1302-67-6)		5			OSHA/TWA, respiratoric dust
SPINEL (1302-67-6)		15			OSHA/TWA, total dust
SPINEL (1302-67-6)		4			WEL long-term, respirable
SPINEL (1302-67-6)		10			WEL long-term, inhalable

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

8.1.3. DNEL/DMEL values

No information.

8.1.4. PNEC values

No information.

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Use good personal hygiene practices – wash hands at breaks and when done working with material.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in areas with increased concentration.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN 166).

Hand protection

Protective gloves (EN 374).

Skin protection

Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345:2011).

Respiratory protection

Not needed under normal use and adequate ventilation. In case of insufficient ventilation wear suitable respiratory protection. Mask with dust filter (P2) or FFP2 (EN 149). Wear a mask with a filter for dust/aerosols - FFP3 (EN 149). 'High/elevated concentrations' means that the occupational exposure limit values have been exceeded.

Thermal hazards

8.2.3. Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

-	Physical state:	solid
-	Colour:	amber
-	Odour:	no odour

Important health, safety and environmental information

-	pH	6 – 9,5
-	Melting point/freezing point	< 2135 °C
-	Initial boiling point/boiling range	No information.
-	Flash point	No information.
-	Evaporation rate	No information.
-	Flammability (solid, gas)	No information.
-	Explosion limits (vol%)	No information.
-	Vapour pressure	No information.
-	Vapour density	No information.
-	Density	Relative density: 3 – 3,4
-	Solubility	No information.
-	Partition coefficient	No information.
-	Auto-ignition temperature	No information.
-	Decomposition temperature	No information.
-	Viscosity	No information.
-	Explosive properties	No information.
-	Oxidising properties	No information.
-	Particle characteristics	No information.

9.2. Other information

-	Solid contents	900 – 1500 g/l
-	Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Product is stable under normal conditions of use, recommended handling and storage conditions.

10.3. Possibility of hazardous reactions

There are no known hazardous reactions.

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage.

10.5. Incompatible materials

Not known.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected.

11. Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

(a) Acute toxicity

Name	Exposure route	Type	Species	Time	Value	Method	Remark
SPINEL (1302-67-6)	dermal	LD₅₀	rat		1000 – 3400 mg/kg
SPINEL (1302-67-6)	inhalation	LC₅₀	rat	4 h	5,1 – 4000 mg/l

(b) Skin corrosion/irritation

No information.

(c) Serious eye damage/irritation

No information.

(d) Respiratory or skin sensitisation

No information.

(e) (Germ cell) mutagenicity

No information.

(f) Carcinogenicity

No information.

(g) Reproductive toxicity

No information.

Summary of evaluation of the CMR properties

No information.

(h) STOT-single exposure

No information.

(i) STOT-repeated exposure

No information.

(j) Aspiration hazard

No information.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information.

11.2.2. Other information

No information.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For components

Substance (CAS Nr.)	Type	Value	Exposure time	Species
SPINEL (1302-67-6)	LC₅₀	35 – 54 mg/L	96 h	fish
	EC₅₀	3,6 – 299 mg/L	2 min	daphnia
	LC₅₀	0,352 – 10 mg/L	14 days	algae

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

No information.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

12.6. Endocrine disrupting properties

No information.

12.7. Additional information

For product

Product is not classified as dangerous for environment.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste.

Packaging

Deliver completely emptied containers to approved waste disposal authorities.

13.1.2. Waste treatment-relevant information

13.1.3. Sewage disposal-relevant information

13.1.4. Other disposal recommendations

14. Transport information

14.1. UN number or ID number

Not applicable.

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

NO.

14.6. Special precautions for user

Not applicable.

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC₅₀ - Lethal Concentration to 50 % of a test population
LD₅₀ - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

List of relevant H phrases

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under Section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.

Naročite profesionalno tiskane etikete na roli

SPINEL

1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name

Synonyms

Name

REACH Registration number

Product code

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Uses advised against

1.3. Details of the supplier of the safety data sheet

Manufacturer

1.4. Emergency telephone number

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

2.2.2. Contains:

2.2.3. Special provisions

2.3. Other hazards

3. Composition/information on ingredients

3.1. Substances

3.2. Mixtures

4. First aid measures

4.1. Description of first aid measures

General notes

Following inhalation

Following skin contact

Following eye contact

Following ingestion

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Skin contact

Eye contact

Ingestion

4.3. Indication of any immediate medical attention and special treatment needed

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

5.3. Advice for firefighters

Protective actions

Special protective equipment for firefighters

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

6.1.2. For emergency responders

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

6.3.2. For cleaning up

6.3.3. Other information

6.4. Reference to other sections

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

7.1.2. Advice on general occupational hygiene

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

7.2.2. Packaging materials

7.2.3. Requirements for storage rooms and vessels

7.2.4. Storage class

7.2.5. Further information on storage conditions

7.3. Specific end use(s)

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational exposure limit values

8.1.2. Information on monitoring procedures

8.1.3. DNEL/DMEL values

8.1.4. PNEC values

8.2. Exposure controls

8.2.1. Appropriate engineering control

8.2.2. Personal protective equipment

8.2.3. Environmental exposure controls

9. PHYSICAL AND CHEMICAL PROPERTIES