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SAFETY DATA SHEET according to Regulation 1907/2006
Product name: ALFA TAB®
Creation date: 6.10.2008 ·
Revision: 18.7.2017 ·
Version: 1
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1. Identification of the substance/mixture and of the company/undertaking
chemius.net/Ge313
1.1. Product identifier
Product name
ALFA TAB®
Name
aluminium oxide (CAS: 1344-28-1, EC: 215-691-6)
REACH Registration number
01-2119529248-35-0068
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
fireproof materials, ceramics, foundry
Uses advised against
No information.
1.3. Details of the supplier of the safety data sheet
Manufacturer
SILKEM, d.o.o.
Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si
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Supplier
SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel.: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si
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1.4. Emergency telephone number
Emergency
112
Supplier
+386 2 7991 214 (7h - 15h)
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
According to the regulation, the chemical is not classified as hazardous.
2.2 Label elements
2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
2.2.3. Special provisions
The product is not classified as dangerous according to regulations.
2.3. Other hazards
No information.
3. Composition/information on ingredients
3.1. Substances
| Name |
CAS
EC
Index |
% |
Classification according to Regulation (EC)
No 1272/2008 (CLP) |
Classification according to directive 67/548/EEC or 99/45/EC |
REACH Registration No. |
| aluminium oxide |
1344-28-1
215-691-6
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99,5 |
not classified |
not classified |
01-2119529248-35-0068 |
3.2. Mixtures
For substances see 3.1.
4. First aid measures
4.1. Description of first aid measures
General notes
When in doubt or if you feel unwell seek medical assistance.
Following inhalation
Leave contaminated area - breathe fresh air. If difficulties with breathing do not stop, search for medical help.
Following skin contact
Wash affected skin areas thoroughly with plenty of water and soap. Take off all contaminated clothing.
Following eye contact
If substance has got into eyes, immediately wash out with plenty of water for several minutes. Seek medical advice.
Following ingestion
Thoroughly rinse mouth and drink water. Do not induce vomiting! Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation
Breathing dust can irritate the respiratory tract.
Symptoms include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness.
Skin contact
Repeated exposure may cause dry skin or cracked skin.
Eye contact
Dust irritates the eyes.
Symptoms may include: rubescence, edema, pain and lachrymation.
Ingestion
May cause abdominal discomfort.
4.3. Indication of any immediate medical attention and special treatment needed
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5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Use the usual extinguishing measures (carbon dioxide (CO2), dry chemical, foam; water spray)
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
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5.3. Advice for firefighters
Protective actions
In case of fire or heating do not breathe fumes/vapours. Cool the endangered containers with water spray.
Special protective equipment for fire-fighters
Select according to conditions and other factors.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment
Use personal protective equipment (Section 8).
Emergency procedures
Prevent dusting.
6.1.2. For emergency responders
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6.2. Environmental precautions
Prevent environmental contamination. Do not allow product to reach water/drains/sewage systems and ground water.
6.3. Methods and material for containment and cleaning up
6.3.1. For containment
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6.3.2. For cleaning up
Take up mechanically and collect in suitable container and dispose according to current regulations. Prevent dusting. Sweep up the dust or even use suitable vacuum cleaner (if possible).
6.3.3. Other information
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6.4. Reference to other sections
See also sections 8 and 13.
7. Handling and storage
7.1. Precautions for safe handling
7.1.1. Protective measures
Measures to prevent fire
Ensure adequate ventilation.
Measures to prevent aerosol and dust generation
Avoid dust formation and do not breathe dust.
Measures to protect the environment
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7.1.2. Advice on general occupational hygiene
Avoid contact with skin and eyes. Do not eat, drink or smoke while working.
7.2. Conditions for safe storage, including any incompatibilities
7.2.1. Technical measures and storage conditions
Keep in well closed containers. Keep in cool and well ventilated area.
7.2.2. Packaging materials
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7.2.3. Requirements for storage rooms and vessels
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7.2.5. Further information on storage conditions
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7.3. Specific end use(s)
Recommendations
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Industrial sector specific solutions
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8. Exposure controls/personal protection
8.1. Control parameters
8.1.1. Occupational Exposure limit values
Exposure limit values (IUCLID)
8.1.2. Information on monitoring procedures
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.
8.1.3. DNEL/DMEL values
No information.
8.1.4. PNEC values
No information.
8.2. Exposure controls
8.2.1. Appropriate engineering control
Substance/mixture related measures to prevent exposure during identified uses
Prevent dusting. Use good personal hygiene practices-wash hands at breaks and when done working with material.
Organisational measures to prevent exposure
Keep eyewash bottles or personal eyewash units available.
Technical measures to prevent exposure
Keep away from food, drink and animal feedingstuffs.
8.2.2. Personal protective equipment
Eye and face protection
Tight fitting protective goggles (EN 166).
Hand protection
Protective gloves (EN 374).
Skin protection
Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory protection.
8.2.3. Environmental exposure controls
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9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
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Physical state: |
solid |
| - |
Colour: |
white |
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Odour: |
Odorless |
Important health, safety and environmental information
| - |
pH |
No information. |
| - |
Melting point/Freezing point |
> 2000 °C |
| - |
Initial boiling point/boiling range |
> 2980 °C |
| - |
Flash point |
No information. |
| - |
Evaporation rate |
No information. |
| - |
Flammability (solid, gas) |
Not flammable. |
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Explosion limits (vol%) |
No information. |
| - |
Vapour pressure |
No information. |
| - |
Vapour density |
No information. |
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Density |
Relative density:
ca. 3,5 |
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Solubility |
Water:
Insoluble |
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Partition coefficient |
No information. |
| - |
Auto-ignition temperature |
No information. |
| - |
Decomposition temperature |
No information. |
| - |
Viscosity |
No information. |
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Explosive properties |
No information. |
| - |
Oxidising properties |
No information. |
10. STABILITY AND REACTIVITY
10.2. Chemical stability
Product is stable under normal conditions according of handling and storage.
10.3. Possibility of hazardous reactions
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10.4. Conditions to avoid
No special precautions required. Consider the directions for use and storage.
10.5. Incompatible materials
Follow the general rule of incompatible chemicals.
10.6. Hazardous decomposition products
Under normal use conditions no hazardous decomposition products are expected.
11. Toxicological information
11.1. Information on toxicological effects
11.1.1. Acute toxicity
For components
| Name |
Exposure route |
Type |
Species |
Time |
Value |
Method |
Remark |
| (1344-28-1)* |
oral
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LD50 |
rat |
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5000 – 10500 mg/kg |
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| (1344-28-1)* |
inhalation
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LC50 |
rat |
1 h |
18 – 18 mg/l |
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| * Source: IUCLID (For information only) |
11.1.2. Skin corrosion/irritation, serious eye damage/irritation
No information.
11.1.3. Respiratory or skin sensitisation
No information.
11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity
Carcinogenicity
No information.
(Germ cell) mutagenicity
No information.
Reproductive toxicity
No information.
Summary of evaluation of the CMR properties
No information.
11.1.5. STOT - single and repeated exposure
No information.
11.1.6. Aspiration hazard
No information.
12. Ecological information
12.1. Toxicity
12.1.1. Acute (short-term) toxicity
Acute toxicity of ingredients (IUCLID)
| CAS |
Species |
| Fish |
Daphnia |
Algae |
| 1344-28-1 |
LC50/96h: 3185 - 478 mg/l * |
EC50/48h: 632 - 18000 mg/l * |
LC50/72h: 10000 - 320 mg/l * |
| Source: IUCLID (For information only) |
12.1.2. Chronic (long-term) toxicity
No information.
12.2. Persistence and degradability
12.2.1. Abiotic degradation, physical- and photo-chemical elimination
No information.
12.2.2. Biodegradation
No information.
12.3. Bioaccumulative potential
12.3.1. Partition coefficient
No information.
12.3.2. Bioconcentration factor (BCF)
No information.
12.4. Mobility in soil
12.4.1. Known or predicted distribution to environmental compartments
No information.
12.4.2. Surface tension
No information.
12.4.3. Adsorption/Desorption
No information.
12.5. Results of PBT and vPvB assessment
No evaluation.
12.6. Other adverse effects
No information.
12.7. Additional information
For product
Do not allow to reach ground water, water courses or sewage system.
Avoid release to the environment.
13. Disposal considerations
13.1. Waste treatment methods
13.1.1. Product / Packaging disposal
Waste chemical
Dispose according to regulations.
- Waste codes / waste designations according to LoW
06 02 99 - wastes not otherwise specified
Packaging
Deliver completely emptied containers to approved waste disposal authorities.
13.1.2. Waste treatment-relevant information
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13.1.3. Sewage disposal-relevant information
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13.1.4. Other disposal recommendations
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14. Transport information
14.1. UN number
not applicable
14.2. UN proper shipping name
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
14.3. Transport hazard class(es)
not applicable
14.4. Packing group
not applicable
14.5. Environmental hazards
NO
14.6. Special precautions for user
not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)
not applicable
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
Abbreviations and acronyms
ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
Key literature references and sources for data
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List of relevant H phrases
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The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national
laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes
other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that
the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18
years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions.
The information given in this SDS is to describe the product only in terms of health and safety requirements and should not,
therefore, be construed as guaranteeing specific properties.
