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SAFETY DATA SHEET according to Regulation 1907/2006
Product name: ALFA-TAB
Creation date: 6.10.2008 ·
Revision: 23.6.2017 ·
Version: 1
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1. Identification of the substance/mixture and of the company/undertaking
chemius.net/Ge313
1.1. Product identifier
Product name
ALFA-TAB
Chemical name
aluminium oxide (CAS: 1344-28-1, EC: 215-691-6)
REACH Registration number
01-2119529248-35-0068
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use
fireproof materials, ceramics, foundry
Uses advised against
No information
1.3. Details of the supplier of the safety data sheet
Manufacturer
SILKEM d.o.o
Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si
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Supplier
SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel.: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si
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1.4. Emergency telephone number
Emergency
112
Supplier
+386 2 7991 208 (7h - 15h)
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to Reg. 1272/2008
According to the regulation, the chemical is not classified as hazardous.
2.2 Label elements
2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
2.2.3. Special provisions
The product is not classified as dangerous according to regulations.
2.3. Other hazards
No information
3. Composition/information on ingredients
3.1. Substances
| Chemical name |
CAS
EC
Index |
% |
Classification according to Regulation (EC) No 1272/2008 [CLP] |
Classification according to directive 67/548/EEC or 99/45/EC |
REACH reg. number |
| aluminium oxide |
1344-28-1
215-691-6
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99,5 |
not classified |
not classified |
01-2119529248-35-0068 |
3.2. Mixtures
For substances see 3.1.
4. First aid measures
4.1. Description of first aid measures
General measures
When in doubt or if symptoms do not disappear seek medical help.
Inhalation
Leave contaminated area - breathe fresh air. If difficulties with breathing do not stop, search for medical help.
Skin contact
Wash thoroughly with plenty of water and soap! Take off all contaminated clothing.
Eye contact
If substance has got into eyes, immediately wash out with plenty of water for several minutes. Seek medical advice.
Ingestion
Thoroughly rinse mouth and drink water. Do not induce vomiting. Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation
Breathing dust can irritate respiratory tract.
Symptoms include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness.
Skin contact
May cause drying/defatting on repeat or prolonged exposure.
Eye contact
Dust irritates the eyes.
Symptoms may include: rubescence, edema, pain and lachrymation.
Ingestion
May cause abdominal discomfort.
4.3. Indication of any immediate medical attention and special treatment needed
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5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Use the usual extinguishing measures (carbon dioxide (CO2), dry chemical, foam; water spray)
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
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5.3. Advice for firefighters
Protective actions
In case of fire or heating do not breathe fumes/vapours. Cool exposed containers with water spray.
Special protective equipment for fire-fighters
Select according to conditions and other factors.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment
Use personal protective equipment (Section 8).
Emergency procedures
Prevent dusting.
6.1.2. For emergency responders
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6.2. Environmental precautions
Prevent environmental contamination. Do not allow product to reach water/drains/sewage systems and ground water.
6.3. Methods and material for containment and cleaning up
6.3.1. For containment
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6.3.2. For cleaning up
Take up mechanically and collect in suitable container and dispose according to current regulations. Prevent dusting. Sweep up the dust or even use suitable vacuum cleaner (if possible).
6.3.3. Other information
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6.4. Reference to other sections
See also sections 8 and 13.
7. Handling and storage
7.1. Precautions for safe handling
7.1.1. Protective measures
Measures to prevent fire
Ensure adequate ventilation.
Measures to prevent aerosol and dust generation
Avoid dust formation and do not breathe dust.
Measures to protect the environment
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7.1.2. Advice on general occupational hygiene
Avoid contact with skin and eyes. Do not eat, drink or smoke while working.
7.2. Conditions for safe storage, including any incompatibilities
7.2.1. Technical measures and storage conditions
Keep in well closed containers. Keep in cool and well ventilated area.
7.2.2. Packaging materials
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7.2.3. Requirements for storage rooms and vessels
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7.2.5. Further information on storage conditions
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7.3. Specific end use(s)
Recommendations
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Industrial sector specific solutions
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8. Exposure controls/personal protection
8.1. Control parameters
8.1.1. Occupational Exposure limit values
Exposure limit values (IUCLID)
8.1.2. Information on monitoring procedures
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.
8.1.3. DNEL values
No information
8.1.4. PNEC values
No information
8.2. Exposure controls
8.2.1. Appropriate engineering control
Substance/mixture related measures to prevent exposure during identified uses
Prevent dusting. Use good personal hygiene practices-wash hands at breaks and when done working with material.
Organisational measures to prevent exposure
Keep eyewash bottles or personal eyewash units available.
Technical measures to prevent exposure
Keep away from food, drink and animal feedingstuffs.
8.2.2. Personal protective equipment
Eye and face protection
Tight fitting protective goggles (EN 166).
Hand protection
Protective gloves (EN 374).
Skin protection
Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).
Respiratory protection
In case of insufficient ventilation wear suitable respiratory protection.
8.2.3. Environmental exposure controls
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9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
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Physical state: |
solid |
| - |
Colour: |
white |
| - |
Odour: |
Odorless |
Important health, safety and environmental information
| - |
pH |
No information |
| - |
Melting point/Freezing point |
> 2000 °C |
| - |
Initial boiling point/boiling range |
> 2980 °C |
| - |
Flashpoint |
No information |
| - |
Evaporation rate |
No information |
| - |
Ignition temperature |
Not flammable. |
| - |
Explosion limits (vol%) |
No information |
| - |
Vapour pressure |
No information |
| - |
Vapour density |
No information |
| - |
Density |
Relative density:
ca. 3,5 |
| - |
Solubility |
Water:
Insoluble |
| - |
Partition coefficient |
No information |
| - |
Auto-ignition temperature |
No information |
| - |
Decomposition temperature |
No information |
| - |
Viscosity |
No information |
| - |
Explosive properties |
No information |
| - |
Oxidising properties |
No information |
10. STABILITY AND REACTIVITY
10.2. Chemical stability
Product is stable under normal conditions according to handling and storage.
10.3. Possibility of hazardous reactions
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10.4. Conditions to avoid
No special precautions required. Consider the directions for use and storage.
10.5. Incompatible materials
Follow the general rule of incompatible chemicals.
10.6. Hazardous decomposition products
Under normal use conditions no hazardous decomposition products expected.
11. Toxicological information
11.1. Information on toxicological effects
11.1.1. Acute toxicity
For components
| Chemical name |
exp. route |
Type |
species |
Time |
value |
Method |
Remark |
| (1344-28-1)* |
oral
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LD50 |
rat |
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5000 – 10500 mg/kg |
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| (1344-28-1)* |
inhalation
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LC50 |
rat |
1 h |
18 – 18 mg/l |
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| * Source: IUCLID (For information only) |
11.1.2. Skin corrosion/irritation, serious eye damage/irritation
No information
11.1.3. Respiratory or skin sensitisation
No information
11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity
Carcinogenicity
No information
(Germ cell) mutagenicity
No information
Reproductive toxicity
No information
Summary of evaluation of the CMR properties
No information
11.1.5. STOT - single and repeated exposure
No information
11.1.6. Aspiration hazard
No information
12. Ecological information
12.1. Toxicity
12.1.1. Acute (short-term) toxicity
Acute toxicity of ingredients (IUCLID)
| CAS |
Species |
| Fish |
Daphnia |
Algae |
| 1344-28-1 |
LC50/96h: 3185 - 478 mg/l * |
EC50/48h: 632 - 18000 mg/l * |
LC50/72h: 10000 - 320 mg/l * |
| Source: IUCLID (For information only) |
12.1.2. Chronic (long-term) toxicity
No information
12.2. Persistence and degradability
12.2.1. Abiotic degradation, physical- and photo-chemical elimination
No information
12.2.2. Biodegradation
No information
12.3. Bioaccumulative potential
12.3.1. Partition coefficient
No information
12.3.2. Bioconcentration factor (BCF)
No information
12.4. Mobility in soil
12.4.1. Known or predicted distribution to environmental compartments
No information
12.4.2. Surface tension
No information
12.4.3. Adsorption/Desorption
No information
12.5. Results of PBT and vPvB assessment
No evaluation.
12.6. Other adverse effects
No information
12.7. Additional information
For product
Do not allow to enter ground water, water course or sewage system.
Avoid release to the environment.
13. Disposal considerations
13.1. Waste treatment methods
13.1.1. Product / Packaging disposal
Waste chemical
Dispose according to regulations.
- Waste codes / waste designations according to LoW
06 02 99 - wastes not otherwise specified
Packaging
Completely emptied containers leave to approved waste disposal authorities in charge.
13.1.2. Waste treatment-relevant information
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13.1.3. Sewage disposal-relevant information
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13.1.4. Other disposal recommendations
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14. Transport information
14.1. UN number
not applicable
14.2. UN proper shipping name
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
14.3. Transport hazard class(es)
not applicable
14.4. Packing group
not applicable
14.5. Environmental hazards
NO
14.6. Special precautions for user
not applicable
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)
not applicable
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
Key literature references and sources for data
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List of relevant H phrases
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The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national
laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes
other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that
the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18
years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions.
The information given in this SDS is to describe the product only in terms of health and safety requirements and should not,
therefore, be construed as guaranteeing specific properties.
