SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name:

Zeolitni težki kompound / Zeolite heavy compound / Zeolith Heavy Compound HC13

Creation date: 1.4.2008 · Revision: 17.11.2014 · Version: 1

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/dSV88

1.1. Product identifier

Product name

Zeolitni težki kompound / Zeolite heavy compound / Zeolith Heavy Compound HC13

Synonyms

HC13

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Industrial use

Uses advised against

No information.

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM, d.o.o.
Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel: +386 2 7991 200
Fax: +386 2 7991 230
E-mail: info@silkem.si

Supplier

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Phone: +386 2 7991 200
Fax: +386 2 7991 230
E-mail: info@silkem.si

1.4. Emergency telephone number

112

+386 2 7991 208 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the product is not classified as hazardous.

Classification according to directive 67/548/EEC or. 99/45/EC

According to the regulation, the product is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

P261  Avoid breathing dust/fume/gas/mist/vapours/spray.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P341  IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

2.2.2. Contains:

-

2.2.3. Special provisions

Irritates eyes and skin.

2.3. Other hazards

No information.

3. Composition/information on ingredients

3.1. Substances

For mixtures see 3.2.

3.2. Mixtures

Name CAS
EC
Index		 % Classification according to Regulation (EC)
No 1272/2008 (CLP)		 Specific Conc. Limits Classification according to directive 67/548/EEC or 99/45/EC REACH Registration No.
Zeolites 1318-02-1
215-283-8
-		 77 Skin Irrit. 2; H315
Eye Irrit. 2; H319		 Xi; R36/38 01-2119429034-49-0017

4. First aid measures

4.1. Description of first aid measures

General notes

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency.

Following inhalation

Remove patient to fresh air - move out of dangerous area. Ventilate the premises. Inhale fresh air. Seek medical help immediately.

Following skin contact

Areas of the body that have come into contact with the product must be rinsed immediately with plenty of running water. If irritation of skin persists seek medical attention.

Following eye contact

Immediately flush eyes with plenty of water while keeping eyelids apart (at least 15 minutes). Consult a physician immediately! Recommendation (based on practical experience): wash with plenty of water or with 3% boric acid solution.

Following ingestion

Rinse mouth thoroughly with water. Drink 2 glasses of water. Do not induce vomiting! In case of doubt or if feeling unwell seek medical help.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Coughing, sneezing, nasal discharge, labored breathing.

Skin contact

On contact with skin causes irritation and redness.

Eye contact

Redness, tearing, pain.

Ingestion

Irritates digestive organs - mouth, gullet, digestive tract.

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Use the usual extinguishing measures (carbon dioxide (CO2), dry chemical, foam; water spray)

Unsuitable extinguishing media

Not available.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

-

5.3. Advice for firefighters

Protective actions

In case of fire or heating do not breathe fumes/vapours.

Special protective equipment for firefighters

-

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8). Wear safety gloves and glasses. Thoroughly clean hands after use or contact.

Emergency procedures

-

6.1.2. For emergency responders

High risk of slipping due to leakage/spillage of product.

6.2. Environmental precautions

Use appropriate containment to dispose waste (according to current regulation-section 13.) If accidental large entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Pick up mechanically and remove it in accordance with regulation.

6.3.3. Other information

-

6.4. Reference to other sections

See also Sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

-

Measures to prevent aerosol and dust generation

Prevent dusting.

Measures to protect the environment

-

7.1.2. Advice on general occupational hygiene

Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational exposure limit values

No information.

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

8.1.3. DNEL/DMEL values

No information.

8.1.4. PNEC values

No information.

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Avoid contact with eyes and skin.

Organisational measures to prevent exposure

Remove all contaminated clothes immediately and wash them before reuse. Keep eyewash bottles or personal eyewash units available.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN ISO 16321-1). Eye wash bottle with clean water.

Hand protection

Use chemical resistant gloves.

Skin protection

Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345:2011). Avoid contact with skin. Shower.

Respiratory protection

Wear suitable protective breathing mask (EN 136) with filter A2-P2 (EN 14387).

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: white
- Odour: odourless

Important health, safety and environmental information

- pH 11 – 12
- Melting point/freezing point No information.
- Initial boiling point/boiling range No information.
- Flash point No information.
- Evaporation rate No information.
- Flammability (solid, gas) No information.
- Explosion limits (vol%) No information.
- Vapour pressure No information.
- Vapour density No information.
- Density Density:
> 2 g/cm3
- Solubility Water:
insoluble
- Partition coefficient No information.
- Auto-ignition temperature No information.
- Decomposition temperature No information.
- Viscosity No information.
- Explosive properties No information.
- Oxidising properties No information.
- Particle characteristics No information.

9.2. Other information

- Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

-

10.2. Chemical stability

Product is stable under normal conditions.

10.3. Possibility of hazardous reactions

-

10.4. Conditions to avoid

Follow directions for use and storage. Protect from moisture and water - keep in dry place.

10.5. Incompatible materials

-

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected.

11. Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

(a) Acute toxicity

NameExposure routeTypeSpeciesTimeValueMethodRemark
For productinhalationLC50rat4 h 18,3 mg/ldust/aerosol
For productdermalLD50rabbit 2000 mg/kg
For productoralLD50rat 10000 mg/kg

(b) Skin corrosion/irritation

No information.

(c) Serious eye damage/irritation

No information.

(d) Respiratory or skin sensitisation

No information.

(e) (Germ cell) mutagenicity

No information.

(f) Carcinogenicity

No information.

(g) Reproductive toxicity

No information.

Summary of evaluation of the CMR properties

No information.

(h) STOT-single exposure

No information.

(i) STOT-repeated exposure

No information.

(j) Aspiration hazard

No information.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information.

11.2.2. Other information

No information.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For product
Type Value Exposure time Species Organism Method Remark
EC50 560 – 1000 mg/L 72 h algae
LC50 1800 – 3200 mg/L 96 h fish

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

No information.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

12.5. Results of PBT and vPvB assessment

No evaluation.

12.6. Endocrine disrupting properties

No information.

12.7. Additional information

For product

Avoid release to the environment.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste.

Waste codes / waste designations according to LoW

06 02 99 - wastes not otherwise specified

Packaging

Deliver completely emptied containers to approved waste disposal authorities.

Waste codes / waste designations according to LoW

15 01 02 - plastic packaging

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number or ID number

Not applicable.

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

NO.

14.6. Special precautions for user

Not applicable.

14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

- Dangerous preparations directive (99/45/EC) as amended

- Dangerous substances directive (67/548/EEC) as amended

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

-

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

MSDS, Silkem d.o.o., ZEOLIT COMPOUND HC13, 10.2.20005, version 2

List of relevant R phrases

R36/38  Irritating to eyes and skin.

List of relevant H phrases

H315  Causes skin irritation.
H319  Causes serious eye irritation.

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under Section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.